hydrogenation of nitrobenzene to aniline

Get the latest research from NIH: https://www.nih.gov/coronavirus. Find NCBI SARS-CoV-2 literature, sequence, and clinical content: https://www.ncbi.nlm.nih.gov/sars-cov-2/. %PDF-1.5 Working off-campus? Sci Rep. 2020 Feb 6;10(1):2039. doi: 10.1038/s41598-020-59003-5. Hydrogenation of nitrobenzene to aniline was carried out at 250°C in a fixed bed flow type reactor. Photodissociation dynamics of nitrobenzene and o-nitrotoluene. For permission to reproduce, republish and Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Reduction treatment at high temperatures has been proved to be an effective way to improve the performance of Pt/CeO2 catalysts by providing additional Ce3+ surface sites and high H-spillover capability. from the ACS website, either in whole or in part, in either machine-readable form or any other form 2 Enabling technologies, microwaves and ultrasound, used both separately and in combination, have successfully increased the reaction rate and reaction yield. Copyright © 2020 Elsevier B.V. or its licensors or contributors. H, under Visible Light Irradiation http://pubs.acs.org/page/copyright/permissions.html. Find more information on the Altmetric Attention Score and how the score is calculated.  |  The prepared magnetic Pd catalyst was tested in nitrobenzene hydrogenation. stream 2b The yield of nitrobenzene reduction to aniline increased from 20% to an almost quantitative yield over a range of alcohols, diols and aminoalcohols. system. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. << /Filter /FlateDecode /S 66 /Length 90 >> 15 0 obj Pd NPs with size 2.2 nm supported on NH2-UiO-66 were prepared. Epub 2019 May 8. 2005 Aug 12;6(8):1537-43. doi: 10.1002/cphc.200500031. 18 0 obj The heterogeneous nature of the catalytic system was confirmed by a hot-filtering test and the catalyst maintained stable performance in 4 repeated cycles. Hydrogenation of nitrobenzene to aniline is an exothermic reaction occurring at 330 C. The reactor product stream contains aniline, water and unreacted reactants nitrobenzene, hydrogen. If you do not receive an email within 10 minutes, your email address may not be registered,  |  The additional Ce3+ far away from Pt, derived from a high-temperature reduction, can adsorb the N-phenylhydroxylamine intermediate more effectively due to its stronger electron-donating ability and in turn promote aniline formation. Framework analysis for the carcinogenic mode of action of nitrobenzene. 3 Todorov AR, Aikonen S, Muuronen M, Helaja J. Org Lett. Hsu CH, Stedeford T, Okochi-Takada E, Ushijima T, Noguchi H, Muro-Cacho C, Holder JW, Banasik M. J Environ Sci Health C Environ Carcinog Ecotoxicol Rev. These metrics are regularly updated to reflect usage leading up to the last few days. Please enable it to take advantage of the complete set of features! J Hazard Mater. , adsc202000127-sup-0001-misc_information.pdf. Electrochemical reduction of nitrobenzene at carbon nanotube electrode. Any queries (other than missing content) should be directed to the corresponding author for the article. It is also found that Na ions with suitable content facilitate the generation and stabilization of surface Ce3+ by charge transfer and help Pt particles to maintain a smaller size. Get article recommendations from ACS based on references in your Mendeley library. Get the latest public health information from CDC: https://www.coronavirus.gov. 2019 May 17;21(10):3764-3768. doi: 10.1021/acs.orglett.9b01205. Authors Elaine A Gelder 1 , S David Jackson, C Martin Lok. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. By continuing you agree to the use of cookies. A high-energy surface is readily reduced to generate more Ce3+ surface sites and oxygen vacancies, not only favoring the dispersion and stabilization of Pt species due to stronger metal–support interaction but also providing more adsorption sites for reactants and intermediates. National Conference on Chemical Process. Electronic Supporting Information files are available without a subscription to ACS Web Editions. Consequently, a 0.25 wt % Pt catalyst, supported on Na-containing CeO2 nanorods and reduced at 600 °C, displays a high level of aniline productivity of 40.8 molAN/gPt/h and excellent stability in nitrobenzene hydrogenation at room temperature. Tada H, Ishida T, Takao A, Ito S, Mukhopadhyay S, Akita T, Tanaka K, Kobayashi H. Chemphyschem. Information about how to use the RightsLink permission system can be found at Files available from the ACS website may be downloaded for personal use only. endobj 2a). Controllable synthesis of VSB-5 microspheres and microrods: growth mechanism and selective hydrogenation catalysis. endobj Affiliation 1 Department of Chemistry, University, Glasgow, Scotland G12 8QQ. endobj In-situ hydrogen utilization through the formic acid decomposition. We use cookies to help provide and enhance our service and tailor content and ads. https://pubs.acs.org/doi/10.1021/acscatal.0c02730, http://pubs.acs.org/page/copyright/permissions.html. The catalysts exhibits a higher selectivity to aniline, with low accumulation of intermediate products. A highly versatile and flexible copper nanoparticle (Cu(0) NPs) catalytic system has been developed for the controlled and selective transfer hydrogenation of nitroarene. You have to login with your ACS ID befor you can login with your Mendeley account. Epub 2007 Feb 15. Users are 2007 Apr-Jun;25(2):155-84. doi: 10.1080/10590500701399234. The maximum conversions were reached after 80 min at 293 K and 303 K (Fig. << /Linearized 1 /L 517583 /H [ 950 168 ] /O 19 /E 99173 /N 4 /T 517225 >> ACS Omega. Key Laboratory of Clean Chemical Technology, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China, Highly Efficient Hydrogenation of Nitrobenzene to Aniline over Pt/CeO, Your Mendeley pairing has expired. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. redistribute this material, requesters must process their own requests via the RightsLink permission endstream J Environ Sci Health C Environ Carcinog Ecotoxicol Rev. The highly dispersed Pd NPs were efficient in the catalytic transfer hydrogenation of nitrobenzene to aniline using forming acid as a hydrogen source under mild reaction conditions in a water medium without base additives or ligands. Experimental studies provide support for a reaction pathway in which the Cu(0) NPs catalysed transfer hydrogenation of nitrobenzene to aniline proceeds via the condensation route. Please check your email for instructions on resetting your password. The high chemoselectivity of both protocols has been proved in experiments on a panel of variously substituted nitroarenes. A pathway of nitrobenzene hydrogenation catalyzed by Pt/CeO2 is also proposed. The liquid phase hydrogenation of nitrobenzene proceeds consecutively in several steps and is employed to the production of aniline, which is usually catalyzed by supported noble metals or Ni-based catalysts [5], [6], [7], [8], [9]. 2007 Feb 14;126(6):064310. doi: 10.1063/1.2435351. NIH  |  The catalyst was recycled successfully for up to 4 cycles without significant loss of catalytic activity. The catalyst was efficient in transfer hydrogenation of nitrobenzene to aniline. Production of aniline by hydrogenation of nitrobenzene. Visible-Light-Photocatalyzed Reductions of N-Heterocyclic Nitroaryls to Anilines Utilizing Ascorbic Acid Reductant. Unraveling the coordination structure-performance relationship in Pt. AN selectivity data under low NB conversion; kinetics test results; effect of reduction temperature, solvent, H2 pressure, and reaction temperature on the catalytic performance; XRD patterns, HRTEM and HAADF-STEM images, Pt particle size statistics, TOF calculations, Ce 3d XPS spectra, Raman spectra, CO2-TPD curves, and the accompanied CO signals; CO-DRIFTS spectra on Pt/CeO2-P; fitting results of CO-DRIFTS spectra, H2 consumption amount from H2-TPR; physicochemical properties of Pt/CeO2-R-600 with different Na ion contents; NB hydrogenation under a high ratio of the catalyst/reactant; AN productivity under different feed mole ratios of NB and NSB; and AOB hydrogenation results (PDF). At 283 K the reaction is slower, but the total amount of nitrobenzene was transformed to aniline. As follows from the examples below, using the proposed method, section of hydrogenated feed containing 0,49 % wt. 2019 Oct 3;10(1):4500. doi: 10.1038/s41467-019-12459-0. 2007 Sep 5;148(1-2):158-63. doi: 10.1016/j.jhazmat.2007.02.021. Front Chem. Ni-based catalysts were widely reported for … Detailed characterizations reveal that the support shape effect of Pt/CeO2 catalysts on nitrobenzene hydrogenation originates from the exposed crystal planes on CeO2 with different reducibilities.

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